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98%Tert-Butyl Peroxy Benzoate

Tert-Butyl peroxybenzoate (TBPB) a chemical compound from the group of peresters. It is often used as a radical initiator in polymerization reactions, such as the production of LDPE from ethylene, and for crosslinking, such as for unsaturated polyester resins.

TBPB is a low volatility ,high purity,liquid, aromatic peroxuester.it is effective as medium of a broad spectrum of monomers e.g .styrene.ethylenn,acrylics.it is also used to cure (copolymerzation) unsaturated resins .

TBPB is a clear light yellow liquid, which is little soluble in water but well in many organic solvents such as ethanol or phthalate.

As peroxo compound, TBPB contains about 8.16 wt% of active oxygen and has a self accelerating decomposition temperature (SADT) of about 60 °C. The SADT is the lowest temperature at which self-accelerating decomposition in the transport packaging can occur within a week, and which should not be exceeded while storage or transportation.[2] TBPB should therefore be stored between minimum 10 °C (below solidification) and maximum 50 °C. Dilution with a high-boiling solvent increases the SADT. The half-life of TBPB, in which 50% of the peroxy ester is decomposed, is 10 hours at 104 °C, one hour at 124 °C and one minute at 165 °C. Amines, metal ions, strong acids and bases, as well as strong reducing and oxidizing agents accelerate the decomposition of TBPB even in low concentrations.[ However, TBPB is one of the safest peresters or organic peroxides in handling. The main decomposition products of tert-butyl peroxybenzoate are carbon dioxide, acetone, methane, tert-butanol, benzoic acid and benzene.

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